Abstract
In order to uniformly distribute SiCp in the aluminium matrix and prepare SiCp/Al composites with high mechanical and damping properties, a preparation method of colloidal dispersion and suction filtration was developed. It was observed from the microstructure of the composites that the SiCp/Al composites prepared by colloidal dispersion and suction filtration method had good interfacial structures, and the interfacial reaction between SiCp and aluminium matrix was effectively inhibited. Tensile mechanical properties at room temperature and damping properties in the temperature range of 25 °C to 300 °C were tested for the SiCp/Al composites with volume fractions of 5% to 10%. The results showed that SiCp/Al composites have excellent mechanical and damping properties when the volume fraction of SiCp was 7%. This is because SiCp were uniformly distributed in the aluminium matrix, and formed a good interfacial bond with the aluminium matrix, which benefitted both the interfacial slip loss and the strengthening effect of SiCp.
Keywords
Introduction
Al matrix composites combine the excellent properties of the reinforcement and Al matrix, and they have high specific strength and stiffness, a low coefficient of thermal expansion, wear resistance, high-temperature resistance, and good processability.1–3 Discontinuous reinforcement-reinforced Al matrix composites are a type of Al matrix composites that have been investigated and used extensively.4–6 They are created by incorporating ceramic particles as a form of discontinuous reinforcement into the Al matrix. Silicon carbide particles (SiCp) are an inexpensive, easily accessible, and high-performing reinforcement. SiCp-reinforced Al matrix (SiCp/Al) composites are widely used in aircraft, armament and civil applications, such as optical precision instruments, vehicle engine pistons and sporting goods, because of their many excellent properties.7–9 However, as science and technology advance continuously, the performance requirements for mechanical equipment on materials rise. To improve the safety, dependability, and service life of the equipment, the material must not only have excellent mechanical properties but also have good damping vibration absorption. 10
Several studies have been conducted by researchers to increase the damping properties of Al matrix composites. 11 Singh et al. 12 prepared titanium oxide (TiO2) and nanocrystalline lithium titanate (Li4Ti5O12) coated core–shell structures of SiC using a novel hydrothermal technique and applied them to Al matrix composites. In order to improve the damping capacity of the Al matrix composites, the stirring friction treatment was used to refine the Al matrix grains and fully disperse the reinforcement particles. Yang et al. 13 investigated the damping properties of in-situ grown carbon nanotubes reinforced Al matrix composite foams. The results demonstrated that the damping capacity of carbon nanotube/Al composite foams was greatly enhanced by the addition of carbon nanotubes. In order to study the damping characteristics of NiTip/6061Al laminar composites, Ding et al. 14 used a rolled composite process to introduce a layer of NiTi particles with phase transition characteristics into a 6061 Al matrix. The results showed that the composites’ low-temperature damping properties were improved by the synergistic interaction of phase transition damping and interfacial damping, while their high-temperature damping properties were improved by the interfacial damping behaviour between particles. Chu et al. 15 prepared SiC fibre-reinforced Al matrix composites and investigated their damping properties. Due to the substantial loss of vibrational energy through slip at interfaces, grain boundaries, and dislocations, the damping properties of the composites were much higher than that of the matrix. Although there are more studies on the damping properties of Al matrix composites, there are fewer studies on the simultaneous improvement of the mechanical properties and the damping properties of Al matrix composites.
Currently, ball milling is the primary technique used for producing SiCp-reinforced Al matrix composites.16–18 However, in order to prevent oxidation of the Al matrix, the ball milling process must be carried out under vacuum or inert gas protection, which results in a complicated and expensive procedure. 19 Additionally, the Al matrix could become harder during the ball milling process, which might change the Al matrix composites’ ability to dampen vibrations. 20 It was the first time we developed colloidal dispersion and suction filtration method to prepare SiCp/Al matrix composites. In this work, in order to simultaneously improve the mechanical and damping properties of Al matrix composites, SiCp/Al composites were prepared by colloidal dispersion and suction filtration method. The effect of SiCp volume content on the mechanical and damping properties of Al matrix composites was investigated.
Experimental
Raw materials
Al powder (purity: ≥99%) provided by Southwest Aluminum Co., Ltd. of China was used as the Al matrix. Table 1 shows the main components of Al powder. SiC particles (purity: ≥99%) provided by Forsman Co. Ltd. of China were used as reinforcement. Hydroxyethyl cellulose (HEC, purity: ≥99.5%) provided by Aladdin Co., Ltd. of China was used as a reagent for the preparation of the colloidal solution. Figure 1 shows the molecular formula of HEC.

Molecular formula of hydroxyethyl cellulose.
Main components of Al powder.
Fabrication of SiCp/Al composites
A schematic diagram of the colloidal dispersion and suction filtration processes used to prepare SiCp/Al composites was shown in Figure 2. The first step was to prepare a colloidal solution. The process involved adding the weighed HEC to distilled water and mechanically agitating it until it completely dissolved, forming a colloidal solution with a mass concentration of around 3 g/L. After that, the SiCp and Al powder will be distributed. SiCp and Al powder were added to the colloidal solution and mechanically stirred to evenly distribute SiCp and Al powder throughout the colloidal solution. The extra colloidal solution was subsequently pumped off. Pouring the colloidal solution mixed with SiCp and Al powder into the mould and using the filtration device to remove the extra colloidal solution produces a well-blended composite powder. This filtration device was made up of a glass filter cartridge, a glass tube, and a vacuum filtration bottle. The glass tube was connected to the filtration bottle by a rack, and the filter cartridge was situated halfway between the glass tube and the vacuum filtration bottle. The composite powder was then sintered in a vacuum environment. The composite powder was placed into a graphite mould and sintered by hot pressing at 680 °C. The composite powder was found to be difficult to fuse at too-low temperatures, while the Al powder would melt and flow out of the mould’s gaps at too-high temperatures. Thus, the optimum sintering temperature was found to be 680 °C. During the sintering process, a pressure of 15 MPa was applied and the pressure was held for 30 minutes. When the furnace temperature was lowered to room temperature following sintering, the SiCp/Al composites were taken out.

Schematic diagram of the process of preparing SiCp/Al composites by colloidal dispersion and suction filtration method.
In SiCp/Al composites, the volume fractions of SiCp were 5%, 7%, and 10%, respectively. The SiCp/Al composites having a volume fraction of 5% SiCp were referred to as SiCp/Al-5 for the sake of simplicity in the following description. The SiCp/Al composites having a volume fraction of 7% SiCp were referred to as SiCp/Al-7. The SiCp/Al composites having a volume fraction of 10% SiCp were referred to as SiCp/Al-10. For comparison, the same preparation procedure was used to produce an Al matrix.
Characterisation
The microstructure and fracture morphology of SiCp/Al composites were characterised using a scanning electron microscope (SEM) with energy dispersive spectrum (EDS). X-ray diffractometers (XRDs) were used to analyse the phase compositions of SiCp/Al composites. The microstructure of the interface between SiCp and Al matrix was observed by transmission electron microscopy (TEM, FEI). The density of SiCp/Al composites was measured according to Archimedes’ law. By dividing the measured density by the theoretical density, relative density was calculated. Using a Vickers hardness tester (load of 1 kg, time of 10 s), the specimens’ Vickers hardness was determined at room temperature. The material's tensile properties at room temperature were tested in accordance with ASTM D3552-12 test standard. The mechanical testing machine used was a WDW-100 type with a 0.001/s strain rate. Each set of specimens for the tensile tests, which were performed on dog-bone-shaped specimens, was tested three times to get the average value. The tested composite fracture surfaces were observed and analysed using SEM. A Q800 dynamic thermal analyser was used to examine the damping properties of composites in single cantilever mode. The test parameters were temperature 25–300 °C, heating rate 5 °C/min, and strain amplitude 4 × 10−5.
Results and discussions
Micromorphology of the original material
Figure 3 shows the SEM micromorphology of the original powders and the mixed powders after colloidal dispersion and suction filtration. The SEM micromorphology of SiC particles is shown in Figure 3(a). SiC particles present sharp points and edges with an average particle size of about 5 μm. It is advantageous for the SiCp/Al composites’ damping properties that this type of polygonal SiCp may develop more interfacial structure with the Al matrix. 21 Figure 3(b) shows the SEM micromorphology of the Al powder. The Al powder was found to be teardrop-shaped, with an average particle size of roughly 20 μm. This might be because pure Al is softer and produces Al powder in the form of teardrop-shaped. The micromorphology of the mixed powders after colloidal dispersion and suction filtration is shown in Figure 3(c). The surface of Al powder has SiCp adsorbed on it, as can be seen. The ability of colloidal solutions to disperse powder is mostly owing to the presence of hydrophilic and non-polar groups in the HEC, as seen in Figure 1. The surface of the powder can be bonded with non-polar groups, and hydrophilic groups can be adsorbed with water molecules, which reduces the surface tension between the powders and the colloidal solution and makes it easier for the powders to disperse in the solution. 22 Additionally, the colloidal solution is viscous and has the ability to adhere tiny SiCp to the surface of the Al powder throughout the pumping filtering process, preventing SiCp from being sucked out. 23

SEM images of original and mixed powders: (a) SiC particles; (b) Al powder; (c) mixed powders after colloidal dispersion and suction filtration.
Microstructure analysis of SiCp/Al composites
Figure 4 shows the microstructure of SiCp/Al composites. The microstructure of SiCp/Al composites with a 5% SiCp volume fraction is shown in Figure 4(a) and (b). It was found that SiCp were uniformly distributed in the Al matrix and formed a tight bind with the Al matrix. Furthermore, it was found that the composites had a dense structure and no pores or flaws. Figure 4(c) and (d) shows the microstructure of SiCp/Al composites with a SiCp volume fraction of 7%. It can also be seen that SiCp were uniformly distributed into the Al matrix and the SiCp/Al composites had a dense structure. As a result, microstructural investigations revealed that when the SiCp volume fraction was less than 7%, the colloidal solution was capable of dispersing SiCp uniformly into the Al powder, resulting in dense SiCp/Al composites. Figure 4(e) and (f) shows the microstructure of SiCp/Al composites with a SiCp volume fraction of 10%. As shown in Figure 4(e) and (f), when the SiCp volume percentage is 10%, holes occur in the composites due to SiCp agglomeration. This is because when the volume percentage of SiCp is too high, the viscosity of the colloidal solution increases, making mixing more difficult during the mechanical mixing process. As a result, SiCp cannot be effectively dispersed through colloidal solution, resulting in SiCp agglomeration in composites. Due to the poor infiltration of the Al solution at the lower preparation temperature (680 °C), the Al solution could not infiltrate into the SiCp agglomerates, resulting in defects in the composites. 24

SEM images of SiCp/Al composites: (a and b) SiCp/Al-5 composites; (c and d) SiCp/Al-7 composites; (e and f) SiCp/Al-10 composites.
In order to further evaluate the interfacial bonding condition between SiCp and the Al matrix, the interface between SiCp and the Al matrix was observed and analysed by TEM, as shown in Figure 5. An enlarged image of the localised area from Figure 5(a) is shown in Figure 5(b). From the figure, it is clear that SiCp and the Al matrix are strongly connected and that there is no evidence of a reaction between SiCp and the Al matrix at the interface of the composites. However, in other research, an interfacial interaction between SiCp and the Al matrix was discovered to form Al4C3. The reaction equation is shown in Eq. (1).
25

TEM images of the interface between SiCp and Al matrix.
Phase composition analysis
Figure 6 shows the XRD diffraction pattern of the Al matrix and SiCp/Al composites. Figure 6(a) shows the XRD pattern of the Al matrix. It was found that only sharp Al peaks were detected in the Al matrix. This occurs as a result of Al having a higher degree of crystallisation, which produces sharper diffraction peaks. Additionally, no other material phases were found in the Al matrix, which further suggests that the colloid has left very little residue there and has had no impact on it. Figure 6(b)–(d) shows the XRD patterns of SiCp/Al composites with different SiCp volume contents. In SiCp/Al composites, SiC peaks were also seen in addition to Al peaks. Moreover, in SiCp/Al composites, there was no sign of the production of Al4C3, an interfacial reaction product between SiCp and Al matrix. This is in agreement with what Figure 5 shows as an observation. Therefore, the SiCp/Al composites prepared by colloidal dispersion and suction filtration effectively avoided the interfacial reaction between the SiCp and Al matrix.

XRD diffraction patterns of Al matrix and SiCp/Al composites: (a) Al matrix; (b) SiCp/Al-5 composites; (c) SiCp/Al-7 composites; (d) SiCp/Al-10 composites.
Figure 7 shows the EDS scanning analysis of SiCp/Al composites. Figure 7(a) shows the SEM image of the scanned area. Figure 7(b)–(d) shows the elemental distribution of the scanned area. Figure 7(b) and (c) shows the distribution of Al and Si elements, respectively. The Si element in Figure 7(c) is from SiCp. It can be seen as a clear outline of Si elements that have a largely uniform distribution. Therefore, the EDS scanning analysis of the microstructure of SiCp/Al composites also showed that SiCp were uniformly distributed in the Al matrix. It further demonstrates that colloidal dispersion and suction filtration are efficient methods for producing SiCp/Al composites with uniformly distributed reinforcement and dense structure.

EDS scanning analysis of the microstructure of SiCp/Al composites: (a) SEM image of the scanned area; (b) Al element distribution map; (c) Si element distribution map; (d) C element distribution map.
Mechanical properties
The Vickers hardness of the Al matrix and SiCp/Al composites with different SiCp volume contents are shown in Figure 8. It can be seen that the Al matrix has a Vickers hardness of 35 HV. However, the Vickers hardness of SiCp/Al increased to 41 HV when 5 vol.-% SiCp was added to the Al matrix. Compared to the Al matrix, the Vickers hardness of the SiCp/Al-5 composites was increased by 17%. Moreover, as the volume content of SiCp increases, the Vickers hardness of SiCp/Al composites also increases. When the SiCp content was 10 vol.-%, the Vickers hardness of SiCp/Al-10 was 50 HV. Compared to the Al matrix, the Vickers hardness of the SiCp/Al-10 composites was increased by 43%. On the one hand, this is because SiCp has a high Vickers hardness. On the other hand, SiCp played a reinforcing role in the Al matrix, which improved the ability of SiCp/Al composites to resist deformation. 27

Vickers hardness of SiCp/Al composites.
The density and mechanical properties of the Al matrix and SiCp/Al composites were tested. Table 2 presents the density and mechanical properties of the Al matrix and SiCp/Al composites. The Al matrix has a density of 2.70 g/cm3, as shown in Table 2. However, after adding SiCp to the Al matrix with contents of 5 vol.-% and 7 vol.-%, respectively, the density of SiCp/Al composites reached 2.71 g/cm3. This is because SiCp has a higher density than Al, increasing the density of SiCp/Al composites. While the content of SiCp was increased to 10 vol.-%, the density of SiCp/Al composites decreased to 2.7 g/cm3. This may be caused by defects in the SiCp/Al-10 composites. The relative density of SiCp/Al composites was examined in order to better analyse the SiCp/Al composites with internal defects. For the Al matrix, the relative density is 100%. For SiCp/Al composites with SiCp volume contents of 5% and 7%, the relative densities were 99.3% and 99.1%, respectively. However, for SiCp/Al composites with a SiCp volume content of 10%, the relative density was 97.5 g/cm3. It is evident that when the SiCp volume content is 10%, the densification of SiCp/Al composites is reduced. This result is consistent with the observations in Figure 4 and the measurements of density. According to the results of tensile mechanical property testing, Young’s modulus, tensile strength, and elongation for SiCp/Al composites with a SiCp volume content of 5% were 80 GPa, 112 MPa, and 16%, respectively. The Young's modulus and tensile strength of the SiCp/Al-5 composites increased by 15% and 75%, respectively, as compared to the Al matrix, while their elongation reduced by 29%. When the volume content of SiCp was 7%, Young’s modulus and tensile strength of SiCp/Al-7 composites reached 83 GPa and 121 MPa, respectively. In addition, they also maintained a 12% elongation at break. This is because SiCp were evenly distributed throughout the Al matrix, which serves as a strong enhancing factor. However, the tensile strength of SiCp/Al-10 composites declined to 93 MPa and its Young’s modulus was only 83 GPa when the volume content of SiCp was 10%. In addition, their elongation at break also exhibits a notable reduction, with a value of 6%. When the volume content of SiCp reached 10%, hole defects started to emerge in SiCp/Al composites, which could easily cause stress concentration to form fracture origins when subjected to external forces and lower the composites’ mechanical properties. 28
Density and tensile mechanical properties of Al matrix and SiCp/Al composites.
Fracture surfaces analysis
The microphotographs of the fracture surfaces of SiCp/Al composites were analysed in order to further study the strengthening effect of SiCp in the Al matrix, as shown in Figure 9. Figure 9(a) and (b) shows the microphotographs of fracture surfaces of SiCp/Al composites with SiCp volume content of 7%. The fracture surfaces of SiCp/Al-7 composites can be found to have a lot of tear ribs and dimples. The Al matrix might fracture in the SiCp/Al-7 composites, resulting in tear ribs, whilst the SiCp might pull out and separate, forming dimples. These indicate that the fracture form of SiCp/Al-7 composites is a ductile fracture. When SiCp/Al composites are subjected to external forces, cracks can appear at the composites’ interface or in the Al matrix. During the crack extension process, it will be deflected along the SiCp interface when it comes into contact with SiCp that has weak interfacial bonding, and it will directly penetrate SiCp when it comes into contact with SiCp that has strong interfacial bonding. As a result, pull-out and pull-off of SiCp occurred at the fracture surfaces of SiCp/Al composites. The presence of SiCp pull-out and pull-off at the fracture surfaces of SiCp/Al composites indicated that SiCp played a better strengthening role.29,30 This is because strong interfacial bonding between SiCp and the Al matrix enhances the load-bearing performance of the SiCp, and weak interfacial bonding can absorb the fracture energy to inhibit crack extension. Figure 9(c) and (d) shows the microphotographs of fracture surfaces of SiCp/Al composites with SiCp volume content of 10%. It is found that there are a large number of holes in the fracture surfaces of SiCp/Al-10 composites. As can be seen in Figure 9(d), these holes are the result of SiCp agglomeration. On the one hand, SiCp agglomeration may result in its inability to play an effective reinforcing role; on the other hand, the holes formed by SiCp agglomeration can easily lead to stress concentration and the formation of crack sources under the action of external forces, reducing the mechanical properties of the composites. Therefore, SiCp/Al-10 composites exhibit poor mechanical properties.

SEM images of the fracture surfaces of SiCp/Al composites: (a and b) SiCp/Al-7 composites; (c and d) SiCp/Al-10 composites.
Damping properties
Its strain and stress phase deviation, the production of inelastic strain, the conversion of elastic vibration energy into other forms of energy, and the creation of energy loss are the factors that create the material's damping properties when it is subjected to external load vibration. The test temperature has a significant impact on the damping properties of Al matrix composites. On the one hand, an increase in test temperature causes the material’s defect activity to increase, which can absorb a significant amount of vibration energy and enhance the material’s damping properties; on the other hand, when the temperature rises, the interfacial bond strength of the composites falls and more energy is lost due to interfacial slide. The damping properties of SiCp/Al composites have been tested in the temperature range of 25–300 °C to investigate the effect of temperature on those properties. Figure 10 shows the damping-temperature curves of SiCp/Al composites at a 5-Hz test frequency. It can be seen that the damping of SiCp/Al composites increases slowly with the test temperature at temperatures below 150 °C. However, the damping of the SiCp/Al composites rapidly increases with the test temperature when the temperature exceeds 150 °C. This is due to the fact that at low temperatures, the interfacial bonding between SiCp and the Al matrix is stronger, and interfacial slip loss has less of an effect on the composites. However, under high-temperature conditions, the interfacial bonding between SiCp and Al matrix weakens and the interfaces are prone to slip loss of energy, which improves the damping performance of the composites. 31 In addition, SiCp volume fraction has a significant effect on the damping properties of SiCp/Al composites. The damping properties of SiCp/Al composites tend to increase and then decrease as the volume fraction of SiCp increases. The SiCp/Al composites exhibit excellent damping properties when the volume fraction of SiCp is 7%.

Damping-temperature curves of SiCp/Al composites.
In the case of weak interfacial bonding between reinforcement and matrix without considering the effect of temperature environment and loading frequency, the maximum value of interfacial contribution to damping can be expressed as Eq. (2)
32
:
For the case of strong interfacial bonding between the reinforcement and the matrix, the maximum value of the interfacial contribution to the damping can be expressed as Eq. (3):
For SiCp/Al composites with different volume contents, the friction coefficients
Conclusion
In this work, in order to simultaneously improve the mechanical and damping properties of Al matrix composites, a colloidal dispersion and suction filtration method was developed to manufacture SiCp/Al matrix composites. The microstructure, mechanical properties and damping properties of the SiCp/Al composites were studied. The main results were as follows:
The colloidal dispersion and suction filtration is an effective method to disperse SiCp in the Al matrix, and SiCp/Al composites with dense structure and no interfacial reaction can be prepared by the colloidal dispersion and suction filtration method. When the volume fraction of SiCp was 7%, the SiCp/Al composites exhibited excellent mechanical properties with Young's modulus, tensile strength and elongation of 83 GPa, 121 MPa and 12%, respectively. The reason for the relatively excellent mechanical properties is that SiCp were uniformly distributed in the Al matrix, where they have a good strengthening effect. The damping properties of SiCp/Al composites tend to increase and then decrease as the volume fraction of SiCp increases. The SiCp/Al composites exhibit excellent damping properties when the volume fraction of SiCp is 7%. This is because SiCp and the Al matrix form a good interfacial bond that enables interfacial slip loss to enhance the composite's damping properties.
Footnotes
Acknowledgements
This work was supported by the Natural Science Basic Research Program of Shaanxi Province (Grant No.: 2023-JC-QN-0612), the Innovation and Entrepreneurship Training Program for College Students (Grant No.: S202310702060) and the Xi’an Association for Science and Technology Youth Talent Support Program (Grant No.: 959202313059).
Declaration of conflicting interests
The authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.
Funding
The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was supported by the Natural Science Basic Research Program of Shaanxi Province (Grant No.: 2023-JC-QN-0612), the Innovation and Entrepreneurship Training Program for College Students (Grant No.: S202310702060) and the Xi’an Association for Science and Technology Youth Talent Support Program (Grant No.: 959202313059).
