The synergistic effects of Fe2O3 with layered double hydroxides (LDH) in ethylene vinyl acetate copolymer/LDH (EVA/LDH) composites have been studied using limiting oxygen index (LOI), UL-94 tests, and cone calorimeter test (CCT). The results from the LOI and UL-94 tests show that the Fe2O3 can also act as flame retardant synergistic agents in the EVA/LDH composites. The CCT data indicated that the addition of Fe2O3 in the EVA/LDH system can greatly reduce the heat release rate, total heat release, carbon monoxide and carbon dioxide.
Jiao, C.M. and Wang, Z.Z. ( 2006). Flame Retardation of Ethylene-Vinyl Acetate Copolymer Using Nano Magnesium Hydroxide and Nano Hydrotalcite, Journal of Fire Sciences, 24: 47-64.
2.
Feng, T. and Li, D.Q. ( 2003). On the Factors Influencing the Crystal Structure and Crystalline Size of Layered Double Hydroxides, Chinese Journal of Applied Chemistry, 20(2): 117-120.
3.
Wang, Z.Z. and Qu, B.J. ( 2001). Studies on Surface Modifiers in Mg(OH)2 Flame Retarded Polyethylene, Journal of Functional Polymer, 14(1): 45-48.
4.
Zhang, M. and Ding, P. ( 2008). A New Method to Prepare Flame Retardant Polymer Composites , Journal of Materials Processing Technology, 208(1-3): 342-347.
5.
Nyambo, C. and Kandare, E. ( 2008). Flame-retarded Polystyrene: Investigating Chemical Interactions Between Ammonium Polyphosphate and MgAl Layered Double Hydroxide, Polymer Degradation and Stability, 93(9): 1656-1663.
6.
Zhao, C.X. and Liu, Y. ( 2008). Synergistic Effect of Ammonium Polyphosphate and Layered Double Hydroxide on Flame Retardant Properties of Poly(vinyl alcohol), Polymer Degradation and Stability, 93(7): 1323-1331.
7.
Zhang, G.B. and Ding, P. ( 2007). Synergistic Effects of Layered Double Hydroxide with Hyperfine Magnesium Hydroxide in Halogen-free Flame Retardant EVA/HFMH/LDH Nanocomposites, Polymer Degradation and Stability, 92(9): 1715-1720.
8.
Ye, L. and Ding, P. ( 2008). Synergistic Effects of Exfoliated LDH with Some Halogen-free Flame Retardants in LDPE/EVA/HFMH/LDH Nanocomposites, Journal of Applied Polymer Science, 107(6): 3694-3701.
9.
Manzi-Nshutia, C. and Hossenlopp, J.M. (2008). Fire Retardancy of Melamine and Zinc Aluminum Layered Double Hydroxide in Poly(methyl methacrylate) , Polymer Degradation and Stability, 93(10): 1855-1863.
10.
Jiao, C.M. and Wang, Z.Z. ( 2006). Irradiation Crosslinking and Halogen-free Flame Retardation of EVA using Hydrotalcite and Red Phosphorus, Radiation Physics and Chemistry, 75(5): 557-563.
11.
Kong, Q.H. and Hu, Y. ( 2006). Influence of Fe-MMT on Crosslinking and Thermal Degradation in Silicone Rubber/Clay Nanocomposites, Polymers for Advanced Technologies, 17(6): 463-467.
12.
Kong, Q.H. and Hu, Y. ( 2006). Synthesis and Properties of Poly(methyl methacrylate)/Clay Nanocomposites Using Natural Montmorillonite and Synthetic Fe-montmorillonite by Emulsion Polymerization, Polymer Composites, 27(1): 49-54.
13.
Zhang, Y. and Hu, Y. ( 2008). Influence of Fe-MMT on the Fire Retarding Behavior and Mechanical Property of (Ethylene-vinyl Acetate Copolymer/ Magnesium Hydroxide) Composite, Polymers for Advanced Technologies, 19(8): 960-966.
14.
Schartel, B. and Bartholmai, M. (2006). Some Comments on the Main Fire Retardancy Mechanisms in Polymer Nanocomposites, Polymers for Advanced Technologies, 17(9-10): 772-777.
15.
Ye, L. and Qu, B.J. ( 2008). Flammability Characteristics and Flame Retardant Mechanism of Phosphate-intercalated Hydrotalcite in Halogen-free Flame Retardant EVA Blends, Polymer Degradation and Stability, 93(5): 918-924.
16.
Grexa, O. and Lübke, H. ( 2001). Flammability Parameters of Wood Tested on a Cone Calorimeter , Polymer Degradation and Stability, 74(3): 427-432.
17.
Fu M.Z. and Qu B.J. (2004). Synergistic Flame Retardant Mechanism of Fumed Silica in Ethylene-vinyl Acetate/Magnesium Hydroxide Blends , Polymer Degradation and Stability, 85: 633-639.
18.
Tang, Y. and Lewin, M. ( 2008). New Aspects of Migration and Flame Retardancy in Polymer Nanocomposites, Polymer Degradation and Stability, 93(11): 1986-1995.
19.
Tang, Y. and Lewin, M. ( 2007). Maleated Polypropylene OMMT Nanocomposite: Annealing, Structural Changes, Exfoliated and Migration, Polymer Degradation and Stability, 92(1): 53-60.
20.
Cai, Y.B. and Hu, Y. (2007). Catalyzing Carbonization Function of Ferric Chloride Based on Acrylonitrile-Butadiene-Styrene Copolymer/Organophilic Montmorillonite Nanocomposites, Polymer Degradation and Stability , 92(3): 490-496.
21.
Tang, Y. and Hu, Y. ( 2002). Preparation and Flammability of Ethylene-vinyl Acetate Copolymer/Montmorillonite Nanocomposites, Polymer Degradation and Stability, 78: 555-559.
22.
Almeras, X. and Le Bras, M. ( 2003). Effect of Fillers on the Fire Retardancy of Intumescent Polypropylene Compounds, Polymer Degradation and Stability , 82(2): 325-331.
23.
Li, Z.Z. and Qu, B.J. (2003). Flammability Characterization and Synergistic Effects of Expandable Graphite with Magnesium Hydroxide in Halogen-free Flame-retardant EVA Blends, Polymer Degradation and Stability, 81(3): 401-408.
24.
Cross, M.S. and Cusack, P.A. (2003). Effects of Tin Additives on the Flammability and Smoke Emission Characteristics of Halogen-free Ethylene-vinyl Acetate Copolymer, Polymer Degradation and Stability, 79(2): 309-318.
25.
Nazaré, S. and Kandola, B. (2002). Use of Cone Calorimetry to Quantify the Burning Hazard of Apparel Fabrics, Fire and Materials, 26(4-5): 191-199.