Mechanism of the reduction in afterburning and thermal efficiency improvement with highly oxygenated fuels in diesel combustion

Highly oxygenated fuels can effectively reduce afterburning in diesel diffusion combustion and improve the degree of constant volume heat release in spite of increases in injection duration due to smaller heating values. The mechanism of afterburning reduction and the structural differences in the diesel fuel spray with changing the oxygen content in the fuel were investigated in a constant volume vessel and analyzed with 3D CFD simulation. The result showed that the equibalance ratio inside the spray decreased with increases in the oxygen content due to lower theoretical air-fuel ratios, promoting the spray combustion after the end of injection. Further, the combustion characteristics and the exhaust gas emissions of the oxygenated fuels were investigated in an experimental single cylinder diesel engine with modern specifications. With increasing oxygen contents, the degree of constant volume heat release increased with reductions in the afterburning, resulting in higher indicated thermal efficiencies. However, the indicated thermal efficiency showed a maximum at around 27 mass% of the oxygen in fuel and further increases in the oxygen contents resulted in lower indicated thermal efficiencies due to larger cooling losses.