Transform Rice Husk and Recycled Polyethylene into High Performance Composites: Using a Novel Compatibilizer to Infiltratively Enhance the Interfacial Interactions
Available accessResearch articleFirst published online November, 2016
Transform Rice Husk and Recycled Polyethylene into High Performance Composites: Using a Novel Compatibilizer to Infiltratively Enhance the Interfacial Interactions
Rice husks are the fine crop residue used to prepare the industrial wood-like products by melt-blending with polymers. However, most wood-like products are highly filled with natural fibers in order to decrease the cost of the products, as it causes weak interfacial compatibility between the natural fibers and polymers. To successfully prepare a high performance wood-like product, the interfacial compatibility is the key problem that need to be solved. Moreover, the interfacial interactions at the gaps and voids around the natural fibers can enhance the interfacial compatibility of the composites. There is little research focusing on the interfacial interactions at these gaps and voids. In this paper, the multi-monomer graft copolymers of polyethylene (GPE) were used as the compatibilizers for the rice husk (RH) highly filled recycled polyethylene (rPE) composites. How the GPE affected the interfacial compatibility of the composites and the resulting mechanical properties, water resistance, thermal stability and rheological properties of rPE/RH composites were investigated. Results show that GPE could enhance the interfacial interactions of rPE/RH composites by infiltrating into the gaps and voids around RH. The strong interfacial interactions of the composites primarily came from the chemical reactions and physical interactions between RH and GPE. The mechanical properties, water resistance and thermal stability of the composites increased with the increase in GPE loadings. The preferable loadings of GPE were approximately at 8 phr. Meanwhile, GPE could improve the processing properties of the composites.
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