Abstract
This study is a non-isothermal analysis of the calendering process using a water based nanofluid with Cu-nanoparticles. The basic flow equations are simplified under the lubrication approximation theory (LAT) and non-dimensionalized. Theoretical velocity and pressure gradient solutions are achieved, and temperature distribution is numerically computed by finite difference method. The impact of nanoparticle volume fraction on pressure distribution, fluid velocity, temperature distribution, power input, and separating force are presented through graphs and discussed. Nanoparticle volume fraction enhances the magnitude of pressure, pressure gradient, and temperature distribution. Power input and roll-separating force also rise for higher nanoparticle volume fraction. Model II of dynamic viscosity of nanofluid has a greater impact on physical parameters as compared to the model I of dynamic viscosity.
Introduction
During the last few decades, the flow of melted polymer through a confined area between two counter-rotating cylinders to produce a sheet/film of required thickness has been thoroughly investigated. Calenders are utilized to manufacture specific surface textures used for various applications. For example, the calendering process is widely used to produce PVC sheets, rubber sheet, floor covering, and rubber tires. Gaskell 1 and McKelvey 2 first theoretically studied the calendering process for an isothermal Newtonian fluid. Zheng and Tanner 3 studied the calendering process with the help of asymptotic and numerical methods for two fluid models, namely, power-law and Phan-Thien-Tanner model. They studied the separation criteria at the exit-plane of the roll. Torner 4 was the first to study both numerically and experimentally the calendering process under the non-isothermal condition. Dobbels and Mewis 5 analyzed the calendering of non-isothermal nip flow under viscous heating and asymmetry. Kiparissides and Vlachopoulus 6 scrutinized the influence of viscous dissipation using Power law and Newtonian models on the calendering process. Middleman 7 and Tadmor and Gogos 8 briefly studied the calendering procedure in their textbooks to discuss polymer processing. Sofou and Mitsoulis 9 , 10 and Mitsoulis and Sofou 11 thoroughly investigated the viscoplastic calendering process. Moreover, Mitsoulis 12 numerically studied calendering viscoplastic sheets having a finite thickness. The main focus was to determine the free surface shapes at the sheet entering and exiting points. Arcos et al. 13 theoretically analyzed the calendering process for a power-law fluid and discussed how the temperature-dependent consistency index and viscous dissipation change the exiting sheet thickness. Siddiqui et al. 14 studied the calendering process influenced by magnetohydrodynamics (MHD) incompressible viscous fluid model and observed that the magnetic field has a great influence on the separation force, power transmitted and other physical parameters. Ali et al. 15 investigated the viscoelastic effects using the FENE-P equation. The study was carried out for a finite sheet thickness. Sajid et al. 16 studied calendering with a third-order fluid and obtained the exact solution for the constitutive equations. Sajid et al. 17 used Rabinowitsch fluid model to study the calendering process with non-isothermal effects. Zahid et al. 18 investigated analytically the roll coating process with a second grade fluid. Both roll and sheet were assumed to be porous. Ali et al. 19 analyzed a non-isothermal couple stress fluid and observed the influence of couple stress parameter on various physical parameters. Atif et al. 20 numerically studied the Oldroyd 4-constant fluid in calendering to analyze the effects of Oldroyd 4-constant parameters on the interesting physical and engineering quantities. Javed et al. 21 adopted the Giesekus model to numerically study the calendering process. Recently, Khaliq and Abbas 22 theoretically analyzed the roll-coating process of viscous nanofluid with Cu-nanoparticles over a flat porous web. The impact of nanoparticle volume fraction with two different nanofluid viscosity models on the physical and operating parameters was discussed. Kanwal et al. 23 employed this same nanofluid model in viscous fluid with Cu-nanoparticles in analizing the blade coating process.
Nanofluids with suspened nanoparticles in a base fluid is usually used to improve heat transfer rate due to the higher nanoparticle thermal conductivity compared with the base fluid. Nanofluids are broadly used for various technological and industrial purposes, for example, biological solutions, polymer melts, gas turbine blades, paints, computer processors, refrigerators, and fuel cells, etc. Recently, nanofluids and heat transfer are studied by many researchers and scientists. A few research articles on these topics are discussed here. Sheikholeslami et al. 24 observed the heat transfer features of nanofluid flowing between two horizontal rotating plates with suction and injection effects and discussed how the nanoparticle volume fraction impacted other physical and thermal parameters. Sheikholeslami et al. 25 analized the heat transfer for a Cu-water nanofluid squeezed between two parallel plates. Pourmehran et al. 26 depicted the unsteady squeezing flow of a nanofluid in between two parallel plates. They also examined the effects of chemical reaction along with convective boundary conditions. Prasad et al. 27 studied the heat and mass transfer for a MHD nanofluid flow restricted by a semi-infinite plate with added radiation absorption effects. They used Cu and TiO2 nanoparticles with water as the base fluid. They found that the radiation absorption and thermodiffusion parameters raise the temperature, velocity, and skin friction. Shehzad et al. 28 depicted the peristaltic transport with mixed convection of nanofluid flow with added heat transfer and viscous dissipation effects. Five different nanoparticles were studied with two effective nanofluid thermal conductivity models. Sheikholeslami 29 numerically studied the CuO-water nanofluid flowing in a porous channel with MHD by applying the mesoscopic method. Bakthavatchalam et al. 30 comprehensively reviewed the heat transfer impacts of nanofluid and ionanofluid compiling both the theoretical and experimental results. Khan and Azam 31 numerically studied unsteady nanofluid flow using the Carreau model to analyze the heat and mass transfer with MHD effects. Azam et al. 32 then studied this nanofluid flow model flowing around an expanding/contracting cylinder with the impact of radiation. Recently, Azam et al. 33 numerically investigated the solar energy impacts on the convective flow of unsteady MHD nanofluid. Azam et al. 34 modeled the radiative-Cross nanofluid to evaluate how the Arrhenius activation energy and thermal radiation impact on the flow past a stretching surface.
Nanocomposite films obtained by melt-mixing the nanoparticles in the polymer matrix have important applications. Espejo et al. 35 studied the nanocomposite films obtained by melt-mixing the nanoparticles in the thermoplastic polymer matrix for greenhouse covering applications. Mallakpour et al. 36 discussed the mechanical, optical, and thermal properties of nanocomposite films formed by mixing poly (vinyl alcohol) with Titania nanoparticles. According to the literature surveyed above, no study analizes the calendering process of a viscous fluid with nanoparticles to produce thin-film with embedded nanoparticles. Here, we theoretically analyze the calendering process of a viscous fluid with nanoparticles contained in the base fluid. Closed-form solutions of velocity and pressure gradient are achieved, and temperature distribution is numerically studied. The nanoparticle volume fraction influence on physical and thermal parameters are presented with graphs and discussed.
Governing equations
Formulation of problem
Figure 1 shows the physical model under study. Two counter rotating cylinders with equal radii are separated by a thin viscous nanofluid film. The constant angular velocity

Calendering geometry with its physical variables.
The velocity field where
Equation (1)–(3) now becomes
The characteristic scales are obtained for the pressure, velocity, and temperature by conducting an order of magnitude method. The scales for
From equation (5), and considering the relationships in equation (9), we get,
Similarly, a comparison between the terms of convection and viscous dissipation in equation (8), is carried out to obtain the characteristic temperature given as
are defined by
Two models for dynamic viscosity.
The corresponding initial and boundary conditions related to equations (1)–(4) are given as
Dimensionless equations
Considering the order of magnitude analysis, the dimensionless equations necessary to solve the calendering process are as follows (see Figure 2)

Geometry with dimensionless coordinates.
and the values of
The boundary conditions satisfying the pressure and pressure gradient are
Additionally, the equation for dimensionless flow rate per unit width is given as
Sheet thickness
The exiting sheet thickness
Problem solution
The exact solution of equation (24) concerning the boundary conditions (26), (27) is as follows
The pressure gradient in equation (32) is still unknown and hence the solution is incomplete. Using equation (34), the value of the pressure gradient is
The domain for this equation is
Now
At last, the equation for velocity profile by putting equation (39) in equation (37), becomes
Applying the transformation
Heat transfer analysis
Finite Difference Method is applied to solve the Energy equation (25), where the derivatives are approximated as follows
Hence, by putting equation (42) values into equation (25), we get
Now, the system (44) with conditions (45)–(48) is solved by tridiagonal matrix algorithm (TDMA) and the code for this numerical technique was made in MATLAB.
Operating variables
The significant engineering variables such as roll-separating force per unit width and power transmitted to the fluid by the roll are given as
Results and discussions
Here, how the nanoparticle volume fraction influences the velocity, pressure gradient, pressure distribution, exiting sheet thickness, force function, power input, and temperature distribution is studied in detail. While our study is general for any nanoparticle (metallic or non-metallic) with base fluid (e.g. water, ethylene glycol (EG), Glycerin, etc.), we use here as an example, the effects of
Figure 3 shows the velocity profile influenced by nanoparticle volume fraction

Velocity profile
Figure 4 displays the velocity profile influenced by nanoparticle volume fraction

Velocity profile
Figures 5

Pressure distribution versus x influenced by nanoparticle volume fraction

Pressure distribution versus x influenced by nanoparticle volume fraction
Figure 7 depicts the pressure distribution influenced by two dynamic viscosity models with

Pressure distribution influenced by two models of dynamic viscosity with
Figures 8 and 9 present the pressure gradient profile influenced by nanoparticle volume fraction

Pressure gradient profile influenced by nanoparticle volume fraction

Pressure gradient profile influenced by nanoparticle volume fraction
In Figure 9, All curves attain maximum value at the entrance point
Figure 10 illustrates the change in the pressure gradient by two models of dynamic viscosity with

Change in pressure gradient for two dynamic viscosity models with
Figures 11 and 12 portray the roll-separating force and power input versus the nanoparticle volume fraction

Roll-separating force versus nanoparticle volume fraction

Power input versus nanoparticle volume fraction
Figures 13 and 14 analyze the temperature profiles

Temperature profile versus Y at five axial locations with

Temperature profile versus Y at five axial locations with

Temperature profile versus Y at four axial locations with

Temperature profile versus Y at four axial locations with
Figures 15 and 16 show similar variation for λ = 0.475.
Figures 17 and 18 are at

Temperature profile versus Y for nanoparticle volume fractions

Temperature profiles for models I, II and Newtonian (
Conclusions
A theoretical study of the calendering process of viscous nanofluid is carried out. The governing equations are simplified by applying lubrication theory. Closed-form solutions are derived for pressure gradient and velocity. The energy equation is solved by employing a numerical finite-difference technique and graphs are plotted. The main results are:
Increasing the nanoparticle volume fraction increases the pressure and pressure gradient. Model II of viscosity gives higher pressure and pressure gradient versus model I. Both the power input and roll-separating force rise for higher nanoparticle volume fraction and have a significantly higher impact with Model II versus Model I. The outcomes Temperature distribution increases with increasing nanoparticle particle volume fraction. Hence nanoparticles help in heat transfer between the rolls. Model II gives a higher temperature profile compared with the model I.
Footnotes
Declaration of Conflicting Interests
The author(s) declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.
Funding
The author(s) received no financial support for the research, authorship, and/or publication of this article.
