Abstract
A laminar flow torch for the support of a helium microwave plasma is described. The microwave-induced plasma (MIP) and associated spectrometer are used as an element-specific detector for gas chromatography. The development, optimization, and characterization of the torch and plasma are described with the use of carbon, hydrogen, and chlorine as model elements. Finally, the application of the MIP as a detector for gas chromatography is tested with a mixture of chlorinated and other solvents, where detector selectivity is demonstrated through observation of the carbon and chlorine atomic emission lines.
Get full access to this article
View all access options for this article.
References
1.
McCormack
A. J.
Tong
S. C.
and
Cooke
W. D
, Anal. Chem. 37 , 1470 (1965 ).
2.
Bache
C. A.
and
Lisk
D. J
, Anal. Chem. 39 , 789 (1967 ).
3.
McLean
W. R.
Stanton
D. L.
and
Penketh
G. E
, Analyst 98 , 432 (1973 ).
4.
Beenakker
C. I. M.
, Spectrochim. Acta 32B , 173 (1977 ).
5.
Beenakker
C. I. M.
, Spectrochim. Acta 31B , 483 (1976 ).
6.
Beenakker
C. I. M.
and
Boumans
P. W. J. M
, Spectrochim. Acta 33B , 53 (1978 ).
7.
Alder
J. F.
Jin
Q.
and
Snook
R. D
, Anal. Chim. Acta 120 , 147 (1980 ).
8.
Alder
J. F.
Jin
Q.
and
Snook
R. D
, Anal. Chim. Acta 172 , 139 (1985 ).
9.
Abdillahi
M. M.
and
Snook
R. D
, Analyst 111 , 265 (1986 ).
10.
Abdillahi
M. M.
Tschanen
W.
and
Snook
R. D
, Anal. Chim. Acta 172 , 139 (1985 ).
11.
Carnahan
J. W.
and
Caruso
J. A
, Anal. Chim. Acta 136 , 261 (1982 ).
12.
Bollo-Kamara
A.
and
Codding
E. G
, Spectrochim. Acta 36B , 973 (1981 ).
13.
Zander
A. T.
and
Hieftje
G. M
, Anal. Chem. 50 , 1257 (1978 ).
14.
Goode
S. R.
Chambers
B.
and
Buddin
N. P
, Appl. Spectrosc. 37 , 439 (1983 ).
15.
Michlewicz
K. G.
and
Carnahan
J. W
, Anal. Chem. 58 , 3122 (1986 ).
16.
Michlewicz
K. G.
and
Carnahan
J. W
, Anal. Chim. Acta. 183 , 275 (1986 ).
17.
Haas
D. L.
and
Caruso
J. A
, Anal. Chem. 57 , 846 (1985 ).
18.
Deutsch
R. D.
and
Hieftje
G. M
, Appl. Spectrosc. 39 , 214 (1985 ).
19.
Bruce
M. L.
Workman
J. M.
Caruso
J. A.
and
Lahti
D. J
, Appl. Spectrosc. 39 , 935 (1985 ).
20.
Bruce
M. L.
and
Caruso
J. A
, Appl. Spectrosc. 39 , 942 (1985 ).
21.
Davies
J.
and
Snook
R. D
, J. Anal. Atom. Spectrom. 1 , 195 (1986 ).
22.
Fortuin
J. M.
, Anal. Chim. Acta , 15 , 521 (1966 ).
23.
Altshuller
A. P.
and
Cohen
I. R
, Anal. Chem. 32 , 802 (1960 ).
24.
Kirkbright
G. F.
and
Snook
R. D
, Appl. Spectrosc. 37 , 11 (1983 ).
